15.10.2010
Meggers Group stellt Titelbild der neuen Angewandten Chemie
Erstes Beispiel einer katalytisch asymmetrischen Koordinationsreaktion - Highlight in Nature Chemistry und ChemCatChem

Cover image for Vol. 49 Issue 43
Angewandte Chemie International Edition
Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
Volume
49, Issue 43 Page 7817 - 8045
The latest issue of Angewandte Chemie International Edition is
available on Wiley Online Library
Cover Picture
Cover Picture: Isomerization-Induced Asymmetric Coordination
Chemistry: From Auxiliary Control to Asymmetric Catalysis (Angew. Chem.
Int. Ed. 43/2010) (page 7817)
Lei Gong, Zhijie Lin, Klaus Harms and Eric Meggers
Article first published online: 2 AUG 2010 | DOI:
10.1002/anie.201004296
Thumbnail image of graphical abstract Catalytic asymmetric
coordination chemistry is made possible by chirality transfer from an
organic ligand with sulfur-centered chirality to a chiral-at-metal
octahedral ruthenium complex. E. Meggers and co-workers describe in
their Communication on page 7955 ff. how
(S)-2-(isopropylsulfinyl)phenol and a more electron-rich methoxy
derivative are capable of inducing and even catalyzing a
chirality-generating trans–cis isomerization of two 2,3′-bipyridine
ligands in the ligand sphere of a ruthenium complex

