Publikationen / Publications

2012

• C. R. Mariappan, M. Gellert, C. Yada, F. Rosciano, B. Roling, 'Grain boundary resistance of fast lithium ion conductors: Comparision between a lithium-ion conductive Li-Al-Ti-P-O-type glass ceramic and a Li_1.5Al_0.5Ge_1.5P₃O₁₂ ceramic', Electrochem. Comm. 14 (2012), 25-28.

    doi: 10.1016/j.elecom.2011.10.022

• B. Roling, M. Drüschler, B. Huber, 'Fast and slow capacitive process taking place at the ionic liquid / electrode interface', Faraday Discus. 154 (2012) 303-311.

    doi: 10.1039.C1FD00088H

    Discussion: doi: 10.1039/C1FD90040D

2011

• J. Krümpelmann, M. Balabajew, M. Gellert, B. Roling, 'Quantitative nanoscopic impedance measurements on silver-ion conducting glasses using atomic force microscopy combined with impedance spectroscopy', Solid State Ionics 198 (2011) 16-21.

    doi:10.1016/j.ssi.2011.07.008

• B. Huber, B. Roling, 'Development of a Ag/Ag+ micro-reference electrode for electrochemical measurements in ionic liquids', Electrochim. Acta 56 (2011) 6569-6572.

   doi: 10.1016/j.elecacta.2011.02.055

• R. Atkin, N. Borisenko, M. Drüschler, S. Z. El Abedin, F. Endres, R. Hayes, B. Huber, B. Roling, 'An in situ STM/AFM and impedance spectroscopy study of the extremely pure 1-butyl-1-methyl-pyrrolidinium tris(pentafluoroethyl)trifluorophosphate / Au(111) interface: potential dependent solvation layers and the herringbone reconstruction', Phys. Chem. Chem. Phys. 13 (2011) 6849-6857.

    doi:10.1039/C0CP02846K

• M. Drüschler, B. Huber, B. Roling, 'On capacitive processes at the interface between 1-ethyl-3-methylimidazolium tris(pentafluoroethyl)-trifluorophosphate and Au(111)', J. Phys. Chem. C 115 (2011) 6802-6808. 

    doi:10.1021/jp200395j

• M. Drüschler, B. Roling 'Commentary on "The interface between Au(111) and an ionic liquid"', Electrochim. Acta 56 (2011) 7243-7245.

    doi: 10.1016/jelecacta.2011.05.099

• B. Roling, 'Commentary on "Nonlinear impedance as possible result of ion-polaron interaction in Cu₂O - Al₂O₃ - SiO₂ glass"', J. Non-Cryst. Solids  357 (2011) 1831-1832.

    doi:10.1016/j.jnoncrysol.2011.01.002

• C. R. Mariappan, C. Yada, F. Rosciano, B. Roling, 'Correlation between micro-structural properties and ionic conductivity of Li1.5Al0.5Ge1.5(PO4)3 ceramics', J. Power Sources  196 (2011) 6456-6464.

    doi:10.1016/j.jpowsour.2011.03.065

• P. V. Menezes, J. Martin, M. Schäfer, H. Staesche, B. Roling, K.-M. Weitzel,  'Bombardment induced ion transport - Part II. Experimental potassium ion conductivities in borosilicate glass', Phys. Chem. Chem. Phys. 13 (2011) 20123 - 20128. 

    doi: 10.1039.c1cp21216h

2010

• M. Drüschler, B. Huber, S. Passerini, B. Roling, 'Hysteresis effects in the potential-dependent double layer capacitance of room temperature ionic liquids at a polycrystalline platinum interface', J. Phys. Chem. C 114 (2010) 3614-3617.

    doi:10.1021/jp911513k

• C. R. Mariappan, B. Roling, 'Mechanism and kinetics of Na+ ion depletion under the anode during electro-thermal poling of a bioactive glass, J. Non-Cryst. Solids 356 (2010) 720-724. 

    doi:10.1016/j.jnoncrysol.2009.03.013

•  C. R. Mariappan, T. P. Heins, B. Roling, 'Electrode polarization in glassy electrolytes: Large interfacial capacitance values and indication for pseudocapacitive charge storage', Solid State Ionics 181 (2010) 859-863.

    Manuscirpt on airXiv:cond-mat

    doi:10.1016.j.ssi.2010.05.011

• M. Schäfer, K. Lange, N. Rohman, A. Schlemmer, H. Staesche, B. Roling, K.-M. Weitzel, 'On the transport of potassium ions through borosilicate glass - a combined experimental and theoretical study', Proc. 2010 IEEE ICSD, Potsdam, Germany, pp. 655-658.
  

• H. Staesche, B. Roling, 'Nonlinear conductivity spectra of glasses and glass ceramics: Analysis of the spectral shape and of the scaling properties', Phys. Rev. B 82 (2010) 134202.

    doi:10.1103/PhysRevB.82.134202

• A. Schirmeisen, A. Taskiran, H. Bracht, B. Roling, 'Ion jump dynamics in nanoscopic subvolumes analyzed by electrostatic force spectroscopy', Z. Phys. Chem. 224 (2010) 1831-1852.

    doi:10.1524/zhpch.2010.0016

• H. Staesche, B. Roling, 'Nonlinear dc and dispersive conductivity of ion conducting glasses and glass ceramics, Z. Phys. Chem. 224 (2010) 1655-1676.

    doi:10.1524/zpch.2010.0018

• J. Krümpelmann, C. R. Mariappan, C. Schober, B. Roling, 'Electrochemical double layers at the interface between glassy electrolytes and platinum: Differentiating between the anode and the cathode capacitance', Phys. Rev. B 82 (2010) 224203.

    doi:10.1103/PhysRevB.82.224203

•  C. R. Mariappan, D. M. Yunos, A. R. Boccaccini, B. Roling, 'Bioactivity of electro-thermally poled silicate glass', Acta Biomater. 5 (2009) 1274-1283.

    doi:10.1016/j.actbio.2008.11.005  

•  S. Haddadpour, M. Mellulis, H. Staesche, C. R. Mariappan, B. Roling, R. Clerac, S. Dehnen, 'Inorganic coordination polymers from selenidotetrelate anions [T₂Se₆]^4- (T = Ge, Sn): Synthesis, structures and ionic conductivity of [K2(H2O)3][MnGe4Se10] and (NMe4)[MSn4Se10] (M = Mn, Fe)', Inorganic Chemistry 48 (2009) 1689-1698.

   doi: 10.1021/ic802170f

• A. Schirmeisen, B. Roling, 'Characterizing ion dynamics in nanoscopic volumes: Time-domain electrostatic force spectroscopy on solid electrolytes', Chemical Monthley 9 (2009) 1103-1112.

    doi: 10.1007/s00706-009-0126-6

•  J. C. Dyre, P. Maass, B. Roling, D. L. Sidebottom, 'Fundamental questions relating to ion conduction in disordered solids', Rep. Prog. Phys. 72 (2009) 046501.

    doi: 10.1088/0034-4884/72/4/046501

•  A. Taskiran, A. Schirmeisen, H. Fuchs, H. Bracht, B. Roling, 'Time-domain electrostatic force spectroscopy on nanostructured lithium-ion conducting glass ceramics: Analysis and Interpretation of Relaxation Times', Phys. Chem. Chem. Phys. 11 (2009) 5499-5505.

    doi: 10.1039/b900175c

•  H. Staesche, S. Murugavel, B. Roling, 'Nonlinear conductivity and permittivity spectra of ion conducting glasses', Z. Phys. Chem. 223 (2009) 1229-1238.

    doi: 10.1524/zpch.2009.6076

• R. Puchta, B. Roling, A. Scheurer, V. Weiskopf, F. Hampel, N. J. R. van Eikema Hommes, H.-U. Hummel, 'Bicyclic diironcryptates with mobile guest cations: A new class of solid ionic conductors', Solid State Ionics 179 (2008) 489-494.

    doi:10.1016/j.ssi.2008.02.060  

•  B. Roling, S. Murugavel, 'Nonlinear ionic conductivity of solid electrolytes', Dielectric Newsletter, Issue Feb. 2008.

• B. Roling, S. Murugavel, A. Heuer, L. Lühning, R. Friedrich, S. Röthel, 'Field-dependent ion transport in disordered solid electrolytes', Phys. Chem. Chem. Phys. 10 (2008) 4211-4226

    (Invited Perspective Article).

    doi:10.1039/b717019j 

• C. R. Mariappan, B. Roling, 'Investigation of bioglass-electrode interfaces after thermal poling', Solid State Ionics 179 (2008) 671-677. 

    doi: 10.1016/j.ssi.2008.04.032

• T. Frömling, M. Kunze, M. Schönhoff, J. Sundermeyer, B. Roling, 'Enhanced lithium transference numbers in ionic liquid electrolytes', J. Phys. Chem. B 112 (2008) 12985-12990.

    doi: 10.1021/jp804097j

• Y. Hamon, P. Vinatier, E.I. Kamitsos, M. Dessauze, C.P.E.    Varsamis, D. Zielniok, C. Roesser, B. Roling, 'Nitrogen flow rate as  a new key parameter for the nitridation of electrolyte thin films', Solid State Ionics 179 (2008), 1223-1226.

    doi: 10.1016/j.ssi.2008.04.005  

•  C. R. Mariappan, B. Roling, 'Thermal poling of 45S5 bioglass and evaluation of in-vitro apatite formation', Solid State Physics (India) 53 (2008) 289-290.

• A. Schirmeisen, A. Taskiran, H. Fuchs, H. Bracht, S. Murugavel, B. Roling, 'Interfacial ionic conduction in a nanostructured glass ceramic', Phys. Rev. Lett. 98 (2007) 225901.

    doi: 10.1103/PhysRevLett.98.225901

•  G. H. Frischat, A. Buksak, G. Heide, B. Roling, 'Transport
  processes in heavy metal fluoride glasses', J. Phys. Chem. Solids 68 (2007) 747-752.

    doi:10.1016/j.jpcs.2007.02.048 

• S. Murugavel, B. Roling, 'Ion transport mechanism in borate glasses: Influence of network structure on non-Arrhenius conductivity', Phys. Rev. B 76 (2007) 180202(R).

    doi:10.1103/PhysRevB.76.180202

• B. Roling, 'Mechanisms of ion transport in amorphous and nanostructured materials', in: 'Charge Transport in Disordered Solids with Applications in Electronics', Ed. S. Baranovski, John Wiley & Sons Ltd., (2006), pp. 379-401.                       http://www.wiley-vch.de/publish/dt/books/bySubjectMS00/bySubSubjectMS20/0-470-09504-0/?sID=ea7f5d6f78104b955d8893ae4af695c6

• N. Kaskhedikar, J. Paulsdorf, M. Burjanadze, Y. Karatas, D. Wilmer, B. Roling, H.-D. Wiemhöfer, 'Ionic conductivity of polymer electrolyte membranes based on polyphosphazene with oligo[propylene oxide] side chains', Solid State Ionics 177 (2006) 703-707.

    doi:10.1016/j.ssi.2006.01.011 

• N.Kaskhedikar, J.Paulsdorf, M.Burjanadze, Y.Karatas, B.Roling, H.-D.Wiemhöfer, 'Polyphosphazene based composite electrolytes', Solid State Ionics 177 (2006) 2699-2704.

    doi:10.1016/j.ssi.2006.05.003 

• A. Heuer, S. Murugavel, B. Roling, 'Nonlinear ionic conductivity of thin solid electrolyte samples: Comparison between theory and experiment', Phys. Rev. B. 72 (2005) 174304.

    doi:10.1103/PhysRevB.72.174304

• C. Karlsson, E. Zanghellini, J. Swenson, B. Roling, D. T. Bowron and L. Börjesson, 'Structure of alkali alkaline-earth silicate glasses from neutron diffraction and vibrational spectroscopy', Phys. Rev. B 72 (2005) 064206.

    doi:10.1103/PhysRevB.72.064206

• S. Murugavel, B. Roling, 'Application of nonlinear conductivity spectroscopy to ion transport in solid electrolytes', J. Non-Cryst. Solids 351 (2005) 2819-2824.

    doi:10.1016/j.jnoncrysol.2005.03.074 

• F. Natrup, H. Bracht, S. Murugavel, B. Roling, 'Cation diffusion and ionic conductivity in soda-lime silicate glasses', Phys. Chem. Chem. Phys. 7 (2005) 2279-2286.

     doi: 10.1039/b502501j 

• B. Roling, 'Feste Ionenleiter: Aktuelle Trends in Materialentwicklung, Charakterisierung und Theorie', Bunsenmagazin 3 (2005) 64-73.

• B. Roling, A. Schirmeisen, H. Bracht, A. Taskiran, H. Fuchs, S. Murugavel, F. Natrup, 'Nanoscopic study of the ion dynamics in a LiAlSiO₄ glass ceramic by means of electrostatic force spectroscopy', Phys. Chem. Chem. Phys. 7 (2005) 1472-1475.

    doi:10.1039/b418501c

• B. Roling, S. Murugavel, 'Bulk and interfacial ionic conduction in a LiAlSiO₄ glass ceramic containing nano- and microcrystallites', Z. Phys. Chem. 219 (2005) 23-33.

• C. R. Mariappan, G. Govindaraj, B. Roling, 'Lithium and potassium ion conduction in A₃TiB'P₃O₁₂ (A=Li, K; B'=Zn, Cd) NASICON-type glasses', Solid State Ionics 176 (2005) 723-729.

    doi:10.1016/j.ssi.2004.11.008

• A. Schirmeisen, A. Taskiran, H. Fuchs, B. Roling, S. Murugavel, H. Bracht, F. Natrup, 'Probing ion transport at the nanoscale: Time-domain electrostatic force spectroscopy on glassy electrolytes', Appl. Phys. Lett. 85 (2004) 2053-2055. ´

    doi:10.1063/1.1790034 

•  S. Murugavel, B. Roling, 'Ion transport at interfaces: An ac conductivity study on glass ceramics containing nanocrystallites', Phys. Chem. Glasses 45 (2004) 134-137.

• S. Murugavel, B. Roling, 'Ionic transport in glassy networks with high electronic polarisability: Conductivity spectroscopic results indicating a vacancy-type ion transport mechanism', J. Phys. Chem. B 108 (2004) 2564-2567.

    doi:10.1021/jp036226g

• S. Murugavel, B. Roling, Comment on 'AC conductivity spectra of alkali tellurite glasses: Composition-dependent deviations from the Summerfield scaling' - Reply, Phys. Rev. Lett. 91 (2003) 049602.

•  M. D. Ingram, B. Roling, 'The concept of matrix-mediated coupling: a new. interpretation of mixed-cation effects in glass', J. Phys.: Cond. Mat. 15 (2003) S1595-S1605.

• G. Helsch, G. H. Frischat, K. Helming, B. Roling, S. Murugavel, 'Textured glass ceramics in the system Li₂O - Al₂O₃ - SiO₂', Phys. Chem. Glasses 44 (2003) 203-215.

•  S. Murugavel, B. Roling, 'Nearly constant dielectric loss of glasses containing different mobile alkali ions', J. Non-Cryst. Solids 330 (2003) 122-127.

• M. Dubiel, B. Roling, M. Füting, 'Ac conductivity and ion transport in K⁺ for Na⁺ ion-exchanged glasses: Exchange experiments below and above the glass transition temperature', J. Non-Cryst. Solids 331 (2003) 11-19.

• B. Roling, 'Hopping dynamics of ions and polarons in disordered materials: On the potential of nonlinear conductivity spectroscopy', J. Chem. Phys. 117 (2002) 1320.

•  B. Roling, C. Martiny, S. Murugavel, Comment on 'Ionic conduction in glass: New information on the interrelation between the Jonscher behavior and the nearly-constant-loss behavior from broadband conductivity spectroscopy' - Reply, Phys. Rev. Lett. 89 (2002) 079602.

• F. Natrup, H. Bracht, C. Martiny, S. Murugavel, B. Roling, 'Diffusion of calcium and barium in alkali alkaline-earth silicate glasses', PCCP 4 (2002) 3225

• S. Murugavel, B. Roling, 'AC conductivity spectra of alkali tellurite glasses: Composition-dependent deviations from the Summerfield scaling', Phys. Rev. Lett. 89 (2002) 195902.

• B. Roling, 'Conductivity spectra of disordered ionic conductors: Calculating the time-dependent mean square displacement of the mobile ions', Dielectrics Newsletter, Issue November 2002.

•  C. Martiny, S. Murugavel, B. Roling, F. Natrup, H. Bracht, M. D. Ingram, 'Mobilities of divalent ions in glass', Glass Technol. 43C (2002) 309-314.

• B. Roling, K. Funke, 'Conductivity spectra of ion conducting materials: On the physical meaning of different scaling approaches and of the BNN relation', Recent Research Developments in Non-Crystalline Solids 2 (2002) 299-310

• D. L. Sidebottom, B. Roling, K. Funke, 'Ionic conduction in solids: Comparing conductivity and modulus representations with regard to scaling properties', Phys. Rev. B 63 (2001) 024301.

• B. Roling, C. Martiny, S. Brückner, 'Ion transport in glass: Influence of the glassy structure on the spatial extent of the nonrandom ion hopping', Phys. Rev. B 63 (2001) 214203.

• B. Roling, 'Mechanical loss spectroscopy on inorganic glasses and glass ceramics', Current Opinion in Solid State and Materials Science 5 (2001) 203.

• B. Roling, C. Martiny, S. Murugavel, 'Ionic conduction in glass: New information on the interrelation between the Jonscher behavior and the nearly-constant-loss behavior from broadband conductivity spectroscopy', Phys. Rev. Lett. 87 (2001) 085901.

• B. Roling, 'Influence of Coulomb interactions on the low-temperature particle dynamics in the random barrier model', PCCP 3 (2001) 5093.

• B. Roling, M. D. Ingram, 'Mixed alkaline-earth effects in ion conducting glasses', J. Non-Cryst. Solids 265 (2000) 113.

• B. Roling, 'Particle dynamics in the random barrier model: Monte Carlo simulations at low temperatures',  Phys. Rev. B  61 (2000) 5993.

• B. Roling, 'Dependence of ionic mobilities in mixed cation glasses on the nature of the mobile cations', Phys. Chem. Glasses 41 (2000) 188.

• B. Roling, C. Martiny, 'Non-universal features of the ac conductivity in ion conducting glasses', Phys. Rev. Lett. 85 (2000) 1274.

• K. Funke, C. Cramer, B. Roling, 'Dynamics of mobile ions in glass - What do conductivity spectra tell us?', Glastech. Ber. Glass Sci. Technol. 73 (2000) 244.

• B. Roling, C. Martiny, 'Low-temperature relaxations in glasses and the thermometer effect', Glastechn. Ber. Glass Sci. Technol. 73 C2 (2000) 410.

• B. Roling, 'What do electrical conductivity and electrical modulus spectra tell us about the mechanisms of ion transport processes in melts, glasses, and crystals?', J.  Non-Cryst. Solids 244 (1999) 34.

• B. Roling, C. Martiny, K. Funke, 'Information on the absolute length scales of ion transport processes in glasses from electrical conductivity and tracer diffusion data', J. Non-Cryst. Solids 249 (1999) 201.

• B. Roling, A. Happe, M. D. Ingram, K. Funke, 'Interrelation between different mixed cation effects in the electrical conductivity and mechanical loss spectra of ion conducting glasses', J. Phys. Chem. B 103 (1999) 4122.

• B. Roling, C. Martiny, 'Spatial extent of non-random ion hopping in single and mixed cation glasses',  Tagungsband, XX. Arbeitstagung des Arbeitskreises Nichtkristalline und Partiellkristalline Strukturen, Wolfersdorf, 1999.

• B. Roling, M. D. Ingram, 'Determination of divalent cation mobilities in glass by dynamical  mechanical thermal analysis (DMTA): evidence for cation coupling effects', Solid State Ionics 105 (1998) 47.

• M. D. Ingram, B. Macmillan, A. J. Pappin, B. Roling, J. M. Hutchinson, 'Effects of pressure on the ionic conductivity of AgI-AgPO₃ and KI-AgPO₃ glasses', Solid State Ionics 105 (1998) 103.

• B. Roling, 'Scaling properties of the conductivity spectra of glasses and supercooled melts', Solid State Ionics 105 (1998) 185.

• K. Funke, B. Roling, M. Lange, 'Dynamics of mobile ions in crystals, glasses and melts', Solid State Ionics 105 (1998) 195.

• B. Roling, M. Meyer, A. Bunde, K. Funke, 'Ionic ac and dc conductivities of glasses with varying modifier content, J. Non-Cryst. Solids 226 (1998) 138.

• B. Roling, M. D. Ingram, 'Analysis of mechanical losses due to ion transport processes in silicate glasses', Phys. Rev. B 57 (1998) 14192

• B. Roling, M. D. Ingram, M. Lange, K. Funke, 'Role of AgI for ionic conduction in AgI-AgPO3 glasses', Phys. Rev. B 56 (1997) 13619.

• B. Roling, A. Happe, K. Funke, M. D. Ingram, 'Carrier concentrations and relaxation spectroscopy: New information from scaling properties of conductivity spectra in ionically conducting glasses', Phys. Rev. Lett. 78 (1997) 2160.

• B. Roling, K. Funke, 'Polaronic transport in vanadium phosphate glasses', J. Non-Cryst. Solids 212 (1997) 1.

• K. Funke, C. Cramer, B. Roling, T. Saatkamp, D. Wilmer, 'Ionic and polaronic glassy conductors: conductivity spectra and implications for ionic hopping in glass',  Solid State Ionics 85 (1996) 293.

• C. Cramer, K. Funke, B. Roling, T. Saatkamp, D. Wilmer, M. D. Ingram, A. Pradel, M. Ribes, 'Ionic and polaronic hopping in glass', Solid State Ionics 86 (1996) 481.

• B. Roling, T. Lauxtermann, K. Funke, 'Formation and direct recombination of Frenkel pairs in silver bromide', Solid State Ionics 51 (1992).