Hauptinhalt

Publications

2023 - (2022) - (2021) - (2020) - (2019) - (2015-2018)

"Trendbericht Anorganik 2024 Teil 2: Nebengruppen und Koordinationschemie, Bioanorganik und mehr"

E. Kreidt, C. G. Werncke, Nachrichten der Chemie 2024, in production.

2023

"Hydrogen Atom Abstraction by Trigonal Alkyl and Aryl Imido Cobalt Complexes – Towards a Structure-Reactivity Relationship"

A. Reckziegel, C. Millidoni, A. O. Basilio, C. G. Werncke, submitted.

"Highly fluorescent dialkyl triel dipyrromethenes"

L. Erlemeier, M. J. Müller, G. Stuhrmann, T. Dunaj, C. G. Werncke,* S.Chatterjee, C. v. Hänisch*, Dalton Trans. 2023, DOI: 10.1039/D3DT03323F.

"A Low-Coordinate Iron Organoazide Complex"

A. Gonzaléz, S. Demeshko, F. Meyer, C. G. Werncke, Chem. Commun. 2023, DOI: 10.1039/D3CC03765G.

"Synthesis and Reactivity of A Linear NHC Stabilised Chromium(I) Silylamide"

A. Gonzalez, T.-Y. Chen, S. Demeshko, F. Meyer, C. G. Werncke, Organometallics 2023, 42, 1198. (link)(Special issue on Early Transition metal chemistry)

"Trendbericht Anorganik 2023 Teil 2: Nebengruppen und Koordinationschemie, Bioanorganik und mehr"

E. Kreidt, C. G. Werncke, Nachrichten der Chemie 2023, 71 (2), 57. (link)

"On the Single Molecule Magnetic Behavior of Linear Iron(I) Arylsilylamides"

R. Weller, M. Atanasov, S. Demeshko, T.-Y. Chen, I. Mohelsky, E. Bill, M. Orlita, F. Meyer, F. Neese, C. G. Werncke, Inorg. Chem. 2023, 62, 3153. (link)

2022

"A Series of Low-Coordinate Iron Selenido Complexes: Reactivity of a Linear Iron(I) Silylamide Towards Selenium"

C. Schneider, S. Ivlev, C. G. Werncke, Eur. J. Inorg. Chem. 2022, e202200706. (link).

"Taming the Stilbene Radical Anion"

G. Sieg, I. Müller, K. Weißer, C. G. Werncke, Chem. Sci. 2022, 13, 13872. (link)

"Reactive Solubilization of Heterometallic Clusters by Treatment of (TrBi3)2– Anions (Tr = Ga, In, Tl) with [Mn{N(SiMe3)2}2]"

J. Rienmüller, A. Schmidt, N. Yutronkie, R. Clérac, C. G. Werncke,* F. Weigend,* S. Dehnen,* Angew. Chem. Int. Ed. 2022, e202210683. (link)

"A Diarsene Radical Anion"

G. Sieg, M. Fischer, F. Dankert, J.-E. Siewert, C. Hering-Junghans,* C. G. Werncke*, Chem. Commun. 2022, 58, 9786. (link)

"Synthesis, Properties and Reactivity of Open-Shell, Linear 3d-Metal(I) Complexes"

C. G. Werncke,* A. Gonzales, Encyclopedia of Inorganic and Bioinorganic Chemistry, 2022. (Invited Chapter) (link)

"Between Imide, Imidyl and Nitrene – An Imido Iron Complex in Two Oxidation States"

S. Reith, S. Demeshko, B. Battistella, A. Reckziegel, C. Schneider, A. Stoy, C. Lichtenberg, F. Meyer, D. Munz,* C. G. Werncke*, Chem. Sci. 2022, 13, 7907. (link).

"Intricate Road to Linear Anionic Nickel(I) Hexamethyldisilazanide [Ni(N(SiMe3)2)2]"

A. Reckziegel, B. Battistella, A. Schmidt, C. G. Werncke, Inorg. Chem. 2022, 61, 7794. (link)

"Trendbericht Anorganik 2022 Teil 2: Nebengruppen und Koordinationschemie, Bioanorganik und mehr"

M. Ringenberg, C. G. Werncke, Nachrichten der Chemie 2022, 70 (2), 52. (link)

"On the Synthesis of a T-shaped Imido Nickel Silylamide and Elusive Trigonal Amido Nickel Complexes"

A. Reckziegel, B. Battistella, C. G. Werncke, Eur. J. Inorg. Chem. 2022, e202101102. (link) (invited contribution to EurJIC Talents Special Collection)

"Synthesis of the Open-Shell 3d-Transition Metal(II) Bis(phosphinidenide) [Mn{P(sIDipp)}2]"

R. Weller, M. Balmer, C. von Hänisch, C. G. Werncke, Dalton Trans. 2022, 51, 1765.(HOT Paper) (link)

"NHC-Stabilized Parent Phosphinidene Adducts of Metal(II) Hexamethyldisilazanides of Manganese – Cobalt and Their Lability in Solution"

R. Weller, A. Gonzalez, H. Gottschling, C. von Hänisch, C. G. Werncke, Z. Allg. Anorg. Chem.  2022, e202100338. (link) (Dedicated to Prof. Dr. D. Fenske on the occasion of his 80th birthday)

"Catalytic 1,3-H Atom Shift of a Terminal Benzylic Alkyne by Iron and Alkali Metal Silylamides − Switching between Allene and Internal Alkyne"

R. Weller, I. Müller, C. G. Werncke, Eur. J. Inorg. Chem. 2022, e202100955. (link)

"High-Spin Carbonyl Complexes of Iron(I) and Cobalt(I)"

C. Schneider, L. Guggolz, C. G. Werncke, Dalton Trans. 2022, 51, 179. (link)

2021

"Cobalt and Iron Stabilized Ketyl, Ketiminyl and Aldiminyl Radical Anions"

G. Sieg, Q. Pessemesse, S. Reith, S. Yelin, C. Limberg, D. Munz, C. G. Werncke, Chem. Eur. J. 2021, 67, 16760. (link)

"Synthesis and Characterisation of a Very Low-Coordinate Diferrous [2Fe-2S]0 Unit"

C. Schneider, S. J. Groß, S. Demeshko, S. Bontemps, F. Meyer, C. G. Werncke, Chem. Commun. 2021, 57, 10751. (link)

"On the Synthesis and Reduction of Trigonal Halide Metal(II) Silylamides of Chromium to Cobalt"

R. Weller, L. Völlinger, C. G. Werncke, Eur. J. Inorg. Chem. 2021, 42, 4383. (link)

"Homoleptic Quasilinear Metal(I/II) Silylamides of Cr – Co with Phenyl and Allyl Functions – Impact of Oxidation State on Secondary Ligand Interactions"

R. Weller, L. Ruppach, A. Shlyaykher, F. Tambornino, C. G. Werncke, Dalton Trans. 2021, 50, 10947. (link)

"Imido Cobalt complexes with Imidyl Radical Character"

A. Reckziegel, M. Kour, B. Battistella, S. Mebs, K. Beuthert, R. Berger, C. G. Werncke, Angew. Chem. Int. Ed. 2021, 60, 14376. (link)

"Quasilinear 3d-Metal(I) Complexes [KM(N(Dipp)SiR3)2] (M = Cr − Co) – Structural Diversity, Solution Behaviour and Reactivity"

          R. Weller, I. Müller, C. Duhayon, S. Sabo-Etienne, S. Bontemps, C. G. Werncke, Dalton Trans. 2021, 50, 4890. (link)

"Very Low Oxidation States in Organometallic Chemistry"

C. G. Werncke, Book Chapter in Comprehensive Organometallic Chemistry IV, Vol.1, Elsevier, 2021. (link)

"A Molecular Low-Coordinate [Fe-S-Fe] Unit in Three Oxidation States"

C. Schneider, S. Demeshko, F. Meyer, C. G. Werncke, Chem. Eur. J. 2021, 27, 6348. (link) (dedicated to Prof. Dr W. Kaim on the occasion of his 70th birthday)

"Reductive Coupling of (Fluoro)-Pyridines by Linear 3d-Metal(I) Silylamides of Cr – Co: A Tale of C–C Bond Formation, C–F Bond Cleavage and a Pyridyl Radical Anion"         

I. Müller, C. G. Werncke, Chem. Eur. J. 2021, 27, 4932. (link)

2020

"Reaction of Alkynes with Quasilinear Metal(I) Silylamides of Chromium to Cobalt − A Comparative Study"

I. Müller, D. Munz, C. G. Werncke, Inorg. Chem. 2020, 59, 9521. (link)

"C−H bond activation by an Imido Cobalt(III) and the Resulting Amido Cobalt(II) Complex"

A. Reckziegel, C. Pietzonka, F. Kraus. C. G. Werncke, Angew. Chem. Int. Ed. 2020, 59, 8527. (link)

"The Ambiguous Behaviour of Diphosphines Towards the Quasilinear Iron(I) Complex [Fe(N(SiMe3)2)2]- – Between Inertness, P−C Bond Cleavage and C−C Double Bond Isomerisation"

C. G. Werncke, I. Müller, Chem. Comm. 2020, 56, 2268. (link)

2019

“Reduction of 2,2’-Bipyridine by Quasi-Linear 3d-Metal(I) Silylamides – A Structural and Spectroscopic Study”

I. Müller, S. Schneider, C. Pietzonka, F. Kraus, C. G. Werncke, Inorganics 2019, 7, 117. (link)

"C-Halide Bond Cleavage by a Two-Coordinate Iron(I) Complex"

C. G. Werncke, J. Pfeiffer, I. Müller, L. Vendier, S. Sabo-Etienne, S. Bontemps, Dalton Trans. 2019, 48, 1757. (link)

2015-2018

“Crystal Structure and Magnetic Characterization of Rare Three-Coordinate phosphine Adducts [M(N(SiMe3)2)2(PCyp3)] with M = MnII, FeII and CoII (Cyp = tricyclopentyl)” 

C. G. Werncke, L. Vendier, S. Sabo-Etienne, J.-P. Sutter, C. Pichon, S. Bontemps, Eur. J. Inorg. Chem. 2017, 2017(6), 1041. (link)

“Ising-Type Magnetic Anisotropy and Slow Relaxation of the Magnetization in Four-Coordinate Amido-Pyridine FeII Complexes”

C. G. Werncke, C. Pichon, S. Bontemps, L. Vendier, C. Duhayon, N. Suaud, C. Martins, N. Guihéry, S. Sabo-Etienne, J.-P. Sutter, Inorg. Chem. 2016, 55, 10969. (link)

"Homoleptic Two-Coordinate Silylamido Complexes of Chromium(I), Manganese(I) and Cobalt(I)"

C. G. Werncke, E. Suturina, P. C. Bunting, L. Vendier, M. Atanasov, F. Neese, J. R. Long, S. Sabo-Etienne, S. Bontemps, Chem. Eur. J. 2016, 22, 1668. (Hot Paper) (link)

“Iron Catalyzed Reduction of CO2 into Methylene: Formation of C–N, C–O, and C–C bonds”

G. Jin, C. G. Werncke, Y. Escudié, S. Sabo-Etienne, S. Bontemps, J. Am. Chem. Soc. 2015, 137, 9563. (link)

“Iron Catalyzed C-H Borylation of Arenes”

T. Dombray, C. G. Werncke, S. Jiang, M. Grellier, L. Vendier, S. Bontemps, J.-B. Sortais, S. Sabo-Etienne, C. Darcel, J. Am. Chem. Soc. 2015, 137, 4062. (link)

“Two-Coordinate Iron(I) Complex [Fe(N(SiMe3)2)2]: Synthesis, Properties and Redox Activity“

C. G. Werncke, P. C. Bunting, C. Duhayon, J. R. Long, S. Bontemps, S. Sabo-Etienne, Angew. Chem. Int. Ed. 2015, 54, 245. (Hot Paper) (link)

Promotion (PhD):

“Direct Proof for a Lower Reactivity of Monomeric vs. Dimeric Oxidovanadium Complexes in Alcohol Oxidation" 
C. G. Werncke, C. Limberg, R. Metzinger, Z. Anorg. Allg. Chem. 2013, 639, 2426.
“Surface-inspired Molecular Vanadium Oxide Catalysts for the Oxidative Dehydrogenation of Alcohols: Evidence for Metal Cooperation and Peroxide Intermediates”, 
C. G. Werncke, C. Limberg, C. Knispel, S. Mebs, Chem. Eur. J. 2011, 17, 12129.
“Haloperoxidase Activity of Oxovanadium(V) Thiobisphenolates” 
C. G. Werncke, C. Limberg, C. Knispel, R. Metzinger, B. Braun, Chem. Eur. J. 2011, 17, 2931.