Main Content
Publications
2026
S. Ringelband, J. Pfeiffer and F. Tambornino*
Eur. J. Inorg. Chem. 2026, accepted.
On Oxalyl Halide Isothiocyanates Part I: Syntheses and IsomerismS. Ringelband, and F. Tambornino*
Eur. J. Inorg. Chem. 2026, accepted. doi:10.1002/ejic.70220
On Oxalyl Halide Isothiocyanates Part II: Decarbonylation and Reactivity StudiesS. Ringelband, F. Tambornino, E. Baker, J. Chandler, A. D. Fortes, C. Goodway, K. Greenough, I. Hickman, C. Howard, S. Parker, M. Schastny, J. Taylor
ACS Health & Safety 2026, accepted.
The practicalities of studying phosgene at a neutron source: safety, collaboration and lessons learned.S. Ringelband, S. F. Parker and F. Tambornino*
Inorg. Chem. 2026, 13, 7071-7081. doi:10.1021/acs.inorgchem.5c05882.
Structural, Thermodynamic, and Spectroscopic Characterization of Diphosgene and TriphosgeneS. Ringelband, J. Pfeiffer, H. Günther, S. Ivlev and F. Tambornino*
Z. Anorg. Allg. Chem. 2026, 652, e202500182. doi:10.1002/zaac.202500182.
Polymorphism in Tetramethylammonium Selenocyanate – Crystal Structures of α-, β-, and γ-[NMe4][SeCN]W. Cao, X.-F. Gao, K. Dollberg, C. Hänisch and F. Tambornino*
Inorg. Chem. 2026, 65, 6923-6930. doi:10.1021/acs.inorgchem.6c00402.
Electronic Structures and Stabilities of Trimethylsilyl-Masked Pnictogen and Chalcogen Complex Anions and Comparisons to Their Hydrides: A Combined Photoelectron Spectroscopy and Computational StudyS. Ringelband, T. Cohen and F. Tambornino*
Inorg. Chem. 2026, asap. doi:10.1021/acs.inorgchem.5c05620.
Preparation and Characterization of Oxalyl DicyanideP. Valtseva, B. Wittwer, D. Leitner, F. R. Neururer, F. Tambornino, A. Schmidt, D. Munz, O. S. Wenger and S. Hohloch*
Chem. Sci. 2026, Advance Article. doi:10.1039/D5SC09069E.
Interplay between ligand field strength and the nephelauxetic effect in chromium(iii) complexes with anionic amido ligandsS. Ringelband, J. Pfeiffer, A. D. Fortes, C. M. Howard, S. F. Parker, A. J. Karttunen and F. Tambornino*
Angew. Chem. Int. Ed. 2026, 65, e17323. doi:10.1002/anie.202517323.
Crystal Structures and Intermolecular Interactions in α- and β-phosgene2025
H. Günther, F. Weigend, X. Xie, W. Cao, X.-F. Gao, X.-B. Wang and F. Tambornino*
Angew. Chem. Int. Ed. 2025, 64(31), e202507543. doi:10.1002/anie.202507543.
A Thorough Characterization of the Tellurocyanate AnionA. Shlyaykher, A. Živković, H. Günther, A. L. Barba, N. H. de Leeuw and F. Tambornino*
Dalton Trans. 2025, 54, 74–88. doi:10.1039/d4dt02830a. (Outside Front Cover)
Synthesis, XRD and DFT studies on Pb[ChCN]2 (Ch = O, S, Se) and Pb[SeCN][OH]S. Hohloch* and F. Tambornino*
Inorg. Chem. 2025, 64, 12900–12917. doi:10.1021/acs.inorgchem.5c01041.
Historical and Recent Developments in the Chemistry of Cyanate CongenersH. Günther, S. Hohloch and F. Tambornino*
ACS Omega 2025, 10, 50153-50162. doi:10.1021/acsomega.5c06668.
Six-Membered Thiolate–Thione Chelate Complexes of Group 10 Elements─Syntheses, Crystal Structures, and NMR StudiesS. Ringelband and F. Tambornino*
Acta Crystallogr. E 2025, 81(10), 987. doi:10.1107/S2056989025008369.
Crystal structure of methyl chloroformateV. Bockmair,* A. Klöck, L. Stanzel, S. Ringelband, F. Tambornino and A. J. Kornath
Dalton Trans. 2025, 54, 17221-17230. doi:10.1039/d5dt02262b.
Structural investigation of the protonation states of sulfamic acidS. Hohloch* and F. Tambornino*
Inorg. Chem. 2025, 64, 12900–12917. doi:10.1021/acs.inorgchem.5c01041.
Historical and Recent Developments in the Chemistry of Cyanate CongenersH. Günther and F. Tambornino*
J. Mol. Struct. 2025, 1332, 141636. doi:10.1016/j.molstruc.2025.141636.
Trityl isocyanate, isothiocyanate and azide – Syntheses, crystallographic studies and Hirshfeld surface analysisA. Shlyaykher and F. Tambornino*
Z. Crystallogr. 2025, 240(1-2), 39. doi:10.1515/zkri-2024-0118.
Synthesis and crystallographic characterization of Cu[SeCN]2024
F. Tambornino*, S. Ringelband, S. F. Parker, C. M. Howard and A. D. Fortes,
Acta Crystallogr. B 2024, 80, 495–503. doi:10.1107/S2052520624007583.
A Comprehensive Characterization of Thiophosgene in the Solid StateE. Gougoula*, J. Pfeiffer, M. Schnell* and F. Tambornino*
Phys. Chem. Chem. Phys. 2024, 26, 25678. doi:10.1039/D4CP02226B.
Rotational conformers and nuclear spin isomers of carbonyl diisothiocyanateI. Zaytseva, H. Waldmann, M. P. Linhart, S. I. Ungermann, F. Tambornino, and C. Hoch*
J. Am. Chem. 2024, 146, 29123–29134. doi:10.1021/jacs.4c11286.
Thermolysis of Cs9MO4 (M = In, Sc): Synthesis, Crystal Structure, Chemical Bonding, and Reactivity of the Subvalent Oxidometalates Cs7MO4 (M = In, Sc)J. Pfeiffer, H. Günther, P. Fuzon, F. Weigend and F. Tambornino*
Chem. Eur. J. 2024, 30, e202401508. doi:10.1002/chem.202401508.
Thiocarbonyl Pseudohalides – The Curious Case of Thiocarbonyl DithiocyanateJ. Pfeiffer, M. Möbs, S. Reith, M. Tallu and F. Tambornino*
J. Molecular. Chem. 2024, 1309, 138198. doi:10.1016/j.molstruc.2024.138198.
Intra- and Intermolecular Hydrogen Bonding in N,N'-Carbonyl bis(carbamates), -(S-thiocarbamates) and N,N'-biscarbamoyl ureasJ. Pfeiffer, C. Trost and F. Tambornino*
J. Molecular. Chem. 2024, 1308, 138079. doi:10.1016/j.molstruc.2024.138079.
Synthesis, crystal structure study and spectroscopic analysis of substituted 2,3-dihydro-2-thioxo-4H-1,3,5-thiadiazin-4-ones2023
Dr. D. Rottschäfer, S. Reith, J. Schwarzmann, Dr. F. Tambornino and Prof. Dr. C. Lichtenberg*
Chem. Eur. J. 2023, 30, e202303363. doi:10.1002/chem.202303363.
Cyclic Hydrocarbon Frameworks Containing Two Bismuth Atoms: Towards 9,10-DibismaanthraceneA. Shlyaykher and F. Tambornino*
Inorg. Chem. 2023, 62(30), 11943–11953. doi:10.1021/acs.inorgchem.3c01345.
Synthesis and Stability of Ammonium Selenocyanate [NH4][SeCN] and Its Reactivity toward Ag[SeCN]J. Pfeiffer, J. P. Wagner* and F. Tambornino*,
Eur. J. Inorg. Chem. 2023, 26, e202300290. doi:10.1002/ejic.202300290.
Photolytic Decarbonylation of Oxalyl Diisothiocyanate in Solid Argon Matrices to syn-anti Carbonyl Diisothiocyanate and its Isomerization, (Highlighted as Cover Picture)D. Leitner, B. Wittwer, F. R. Neururer, M Seidl, F. Tambornino and S. Hohloch*
Organometallics 2023, 42(12), 1411–1424. doi:10.1021/acs.organomet.3c00056.
Expanding the Utility of Beta-Diketiminate Ligands in Heavy Group VI Chemisty of Molybdenum and TungstenJ. Pfeiffer, H. Günther, L. Völlinger, D. Botros, B. Scheibe, M. Möbs, F. Kraus, F. Weigend and F. Tamborino*
Chem. Eur. J. 2023, e202203983. doi:10.1002/chem.202203983.
Double addition vs. ring closure: Systematic reactivity study of CO(NCO)2 and CO(NCS)2 towards hydrogen halides, (Highlighted as Cover Picture)2022
T. Hohl, F. Tambornino and C. Hoch*
Crystals 2022, 12(11), 1679. doi:10.3390/cryst12111679.
Structure and Bonding in CsNa2Hg18, a New Ternary Amalgam with Strong Coulombic Bonding ContributionsA. Shlyaykher, T. Pippinger, T. Schleid, O. Reckeweg and F. Tambornino*
Z. Kristallogr. – Cryst. Mater. 2022, 237(1–3), 69–75. doi:10.1515/zkri-2022-0015.
Syntheses, crystallographic characterization and structural relations of Rb[SCN]L. Nusser, T. Hohl, F. Tambornino and C. Hoch*
Z. Anorg. Allg. Chem. 2022, 648(10), e202100389. doi:10.1002/zaac.202100389.
The Cesium Oxide Mercuride Cs18Hg8O6, (Highlighted as Front Cover)F. Tambornino and C. Hoch*
Austr. J. Chem. 2022, 75(8,9), 587–594. doi:10.1071/CH21336.
Crystal structure of the dodecanuclear coordination compounds [RE12(DMF)24(HCOO)8(OH)16]I3 · 4 DMF (RE = Eu, Nd)2021
A. Shlyaykher, M. Ehmann, A. J. Karttunen and F. Tambornino*
Chem. Eur. J. 2021, 27(54), 13552–13557. doi:10.1002/chem.202102058.
A Comprehensive Study on the Full Series of Alkali Metal Selenocyanates AI[SeCN] (AI = Li – Cs), (Highlighted as Inside Cover)R. Weller, L. Ruppach, A. Shlyaykher, F. Tambornino and C. G. Werncke*
Dalton Trans. 2021, 50, 10947–10963. doi:10.1039/D1DT01543E.
Homoleptic Quasilinear Metal(I/II) Silylamides of Cr – Co with Phenyl and Allyl Functions – Impact of Oxidation State on Secondary Ligand InteractionsJ. Pfeiffer, C. Trost, A. Pachkovska, and F. Tambornino*
Inorg. Chem. 2021, 60, 10722–10728. doi:10.1021/acs.inorgchem.1c01421.
A Crystallographic, Spectroscopic, and Computational Investigation of Carbonyl and Oxalyl DiisothiocyanateF. Pan, S. Wei, L. Guggolz, A. R. Eulenstein, F. Tambornino and S. Dehnen*
J. Am. Chem. Soc. 2021, 143(18), 7176–7188. doi:10.1021/jacs.1c02653.
Insights into Formation and Relationship of Multimetallic Clusters: On the Way toward Bi-Rich NanostructuresF. A. Watt, L. Burkhardt, R. Schoch, S. Mitzinger, M. Bauer, F. Weigend*, F. Tambornino*, J. M. Goicoechea* and S. Hohloch*
Angew. Chem. Int. Ed. 2021, 60(17), 9534–9539. doi:10.1002/anie.202100559.
η3‐Coordination and Functionalization of the 2‐Phosphaethynthiolate Anion at Lanthanum(III)B. Peters, M. Möbs, M. Nick, F. Tambornino and S. Dehnen*
ChemistryOpen 2021, 10, 227–232. doi:10.1002/open.202000287.
Ionic Liquid-Driven Formation of and Cation Exchange in Layered Sulfido Stannates – a CH2 Group Makes the Difference2020
E. Geringer, E. Leusmann, F. Tambornino, M. Gerhard, M. Koch and S. Dehnen*
Chem. Comm. 2020, 56, 4769. doi:10.1039/d0cc01887b.
Trapping of ZnCl2 by bipyridyl-functionalized organotin sulfide clusters, and its effect on optical propertiesN. Dehnhardt, C. Berthold, K. Dollberg, F. Tambornino and J. Heine*
Z. Krist. 2020, 235, 8-9. doi:10.1515/zkri-2020-0021.
Synthesis and crystal structures of two layered Cu(I) and Ag(I) iodidometalates2019
F. Tambornino, Q. Yuan, J. M. Goicoechea,* B. Chen and X.-B Wang*
Angew. Chem. Int. Ed. 2019, 58, 15062. doi:10.1002/anie.201906904.
Photoelectron Spectroscopy and Theoretical Studies of PCSe−, AsCS−, AsCSe−, and NCSe−: Insights into the Electronic Structures of the Whole Family of ECX− Anions (E = N, P, As; X = O, S, Se) (Highlighted as Frontispiz)F. Tambornino, E. E. L. Tanner, H. M. A. Amin, J. Holter, T. Claridge, R. G. Compton* and J. M. Goicoechea*
Eur. J. Inorg. Chem. 2019, 11-12, 1644. doi:10.1002/ejic.201801503.
Electrochemical Oxidation of the Phospha- and Arsaethynolate Anions, PCO− and AsCO−2018
F. Tambornino, A.Hinz, R. Köppe and J. M. Goicoechea*
Angew. Chem. Int. Ed. 2018, 57, 8230. doi:10.1002/anie.201805348.
A General Synthesis of Phosphorus- and Arsenic-Containing Analogues of the Thio- and Seleno-Cyanate Anions2017
F. Tambornino and C. Hoch
Z. Kristallogr. 2017, 232, 557. doi:10.1515/zkri-2016-2036.
The simplest representative of a complex series: The Hg-rich amalgam Yb11Hg542016
F. Tambornino, J. Sappl, F. Pultar, T. M. Cong, S. Hübner, T. Giftthaler and C. Hoch*
Inorg. Chem. 2016, 55, 11551. doi:10.1021/acs.inorgchem.6b02068.
Electrocrystallization - a synthetic method for new intermetallic phases with polar metal-metal bondingM. Wörsching, F. Tambornino, S. Datz and C. Hoch*
Angew. Chem. 2016, 128, 11026. doi:10.1002/ange.201605113.
Angew. Chem. Int. Ed. 2016, 55, 10868. doi:10.1002/anie.201605113.
Chemical Twinning of Salt and Metal in the Subnitridometalates Ba23Na11(MN4)4 with M = V, Nb, TaF. Tambornino, K. Schwärzer and C. Hoch*
J. Solid State Chem. 2016, 242, 162. doi:10.1016/j.jssc.2016.07.001.
Synthesis and characterization of La11+xHg45-x and RE11Hg44.5 (RE = Nd, Sm) as hettotypes of the Sm11Cd45 structure typeA. Schmidt, P. Köstler, F. Tambornino and T. Bein*
Micropor. Mesopor. Mat. 2016, 223, 219. doi:10.1016/j.micromeso.2015.10.015.
Efficient Functionalization of Mesoporous MCM-41 with Aromatic Organo-Lithium Reagents2015
A. Marchuk, S. Wendl, N. Imamovic, F. Tambornino, D. Wiechert, P.J. Schmidt and W. Schnick*
Chem. Mater. 2015, 27, 6432. doi:10.1021/acs.chemmater.5b02668.
Nontypical Luminescence Properties and Structural Relation of Ba3P5N10X : Eu2+ (X = Cl, I): Nitridophosphate Halides with Zeolite-like StructureF. Tambornino and C. Hoch*
Z. Anorg. Allg. Chem. 2015, 641, 537. doi:10.1002/zaac.201400561.
The Mercury-richest Europium Amalgam, Eu10Hg55F. Tambornino and C. Hoch*
J. Alloys Compd. 2015, 618, 299. doi:10.1016/j.jallcom.2014.08.173.
Bad metal behaviour in the new Hg-rich amalgam KHg6 with polar metallic bondingF. Tambornino, J. Sappl and C. Hoch*
J. Alloys Compd. 2015, 618, 326. doi:10.1016/j.jallcom.2014.08.017.
The Gd14Ag51 structure type and its relation to some complex amalgam structures2014
F. Tambornino, P. Bielec and C. Hoch*
Acta Cryst. 2014, E70, i27. doi:10.1107/S1600536814010307.
Redetermination of [EuCl2(H2O)6]Cl2013
R. Frankovsky, H. Luetkens, F. Tambornino, A. Marchuk, G. Pascua, A. Amato, H.-H. Klauss and D. Johrendt*
Phys. Rev. B 2013, 87, 174515. doi:10.1103/PhysRevB.87.174515.
Short-range magnetic order and effective suppression of superconductivity by manganese doping in LaFe1-xMnxAsO1-yFy